Synthesis, Characterization And Finger Print Application Of Zn(II) And Cobalt(II) Complexes With Schiff Base Ligands Derived From benzene-1,2-diamine
Main Article Content
Keywords
o-phenene, Schiffbase, Zinc acetate and cobalt chloride
Abstract
Reaction of the o-phenene diamine with tert-butyl-salcyldehyde or p-dimethylaminobenzaldehyde to form Schiffbase 6,6'-(-(1,2-phenylenebis(azaneylylidene))bis(methaneylylidene))bis(2,4-di-tert-butylphenol)(L1) and 4,4'-(1,2-phenylenebis(azaneylylidene))bis(methaneylylidene))bis(N,N-dimethylaniline) (L2) . L1 was react with one mole of Zinc acetate to form ZnL1(1) while L2 react with one mole of zinc acetate or cobalt chloride afforded {ZnL2(CH3COO)2}(2) and {ZnL2Cl2}(3). These complexes employed as colorant for finger print application the medium activity were achieved.
References
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2. M. Tümer, B. Erdogan, H. Köksal, S. Serin, and M. Y. Nutku, "Preparation, spectroscopic characterisation and thermal analyses studies of the Cu (II), Pd (II) and VO (IV) complexes of some Schiff base ligands," Synthesis and reactivity in inorganic and metal-organic chemistry, vol. 28, pp. 529-542, 1998.
3. X. Wang, K. Q. Zhao, Y. Al‐Khafaji, S. Mo, T. J. Prior, M. R. Elsegood, et al., "Organoaluminium complexes derived from anilines or Schiff bases for the ring‐opening polymerization of ε‐caprolactone, δ‐valerolactone and rac‐lactide," European Journal of Inorganic Chemistry, vol. 2017, pp. 1951-1965, 2017.
4. H. H. Essa, F. Kandil, and A. Falah, "Synthesis and identification of Schiff bases and bilogical activity new study," Iraqi Journal of Science, vol. 53, 2012.
5. C. Wei and C.-J. Li, "A highly efficient three-component coupling of aldehyde, alkyne, and amines via C− H activation catalyzed by gold inwater," Journal of the American Chemical Society, vol. 125, pp. 9584-9585, 2003.
6. Y. Al-Khafaji, N. Abd Alrazzak, S. T. Saad, A. S. Abbas, and M. Merdan, "Aluminium complexes as catalysts for ring-opening polymerization of ε-caprolactone bearing Schiff base ligands derived from 4,4′-Methylenebis (2,6-diisopropylaniline)," Journal of Physics: Conference Series, vol. 1234, p. 012055, 2019/07/01 2019.
7. W. Guangbin, "Studies on Cu(II), Zn(II), Ni(II) and Co(II) complexes derived from two dipeptide Schiff Bases," Spectroscopy Letters, vol. 32, pp. 679-688, 1999/07/01 1999.
8. A. Julius, R. Vedasendiyar, A. Devakannan, S. Rajaraman, B. Rangasamy, and V. Saravanan, "Effect of hesperidin for its anti-proliferative activity on liver cancer and cardio vascular diseases," Research Journal of Pharmacy and Technology, vol. 10, pp. 307-308, 2017.
9. N. Kumar, A. Balamurugan, P. Balakrishnan, K. Vishwakarma, and K. Shanmugam, "Biogenic nanomaterials: synthesis and its applications for sustainable development," Biogenic Nano-Particles and their Use in Agro-ecosystems, pp. 99-132, 2020.
10. A. Davoodnia, S. Allameh, A. Fakhari, and N. Tavakoli-Hoseini, "Highly efficient solvent-free synthesis of quinazolin-4 (3H)-ones and 2, 3-dihydroquinazolin-4 (1H)-ones using tetrabutylammonium bromide as novel ionic liquid catalyst," Chinese Chemical Letters, vol. 21, pp. 550-553, 2010.
11. Y. F. Al-Khafaji, M. R. Elsegood, J. W. Frese, and C. Redshaw, "Ring opening polymerization of lactides and lactones by multimetallic alkyl zinc complexes derived from the acids Ph 2 C (X) CO 2 H (X= OH, NH 2)," RSC advances, vol. 7, pp. 4510-4517, 2017.
12. S. Goel and K. Lal, "Studies on Metal Complexes of Schiff Bases Derived from Sulphadiazine and Sulphadimidine with 5-Substituted Salicylaldehydes," Asian Journal of Chemistry, vol. 2, p. 271, 1990.
13. B. Naureen, G. Miana, K. Shahid, M. Asghar, S. Tanveer, and A. Sarwar, "Iron (III) and zinc (II) monodentate Schiff base metal complexes: Synthesis, characterisation and biological activities," Journal of Molecular Structure, vol. 1231, p. 129946, 2021.
14. A. Singh, S. K. Maiti, H. P. Gogoi, and P. Barman, "Purine-based Schiff base Co (II), Cu (II), and Zn (II) complexes: Synthesis, characterization, DFT calculations, DNA binding study, and molecular docking," Polyhedron, vol. 230, p. 116244, 2023.
15. N. K. Meher, P. K. Verma, and K. Geetharani, "Cobalt-Catalyzed Regioselective 1, 2-Hydroboration of N-Heteroarenes," Organic Letters, 2023.
16. O. Khaoua, N. Benbellat, S. Zeroual, S. Mouffouk, S. Golhen, A. Gouasmia, et al., "Combined experimental, computational studies (synthesis, crystal structural, DFT calculations, spectral analysis) and biological evaluation of the new homonuclear complex Di-μ-benzoato-bis [benzoatodipyridine-cobalt (II)]," Journal of Molecular Structure, vol. 1273, p. 134331, 2023.
17. R. Sandaroos, B. Maleki, S. Naderi, and S. Peiman, "Efficient synthesis of sulfones and sulfoxides from sulfides by cobalt-based Schiff complex supported on nanocellulose as catalyst and Oxone as the terminal oxidant," Inorganic Chemistry Communications, vol. 148, p. 110294, 2023.
18. M. Michelas, Y. K. Redjel, J.-C. Daran, M. Benslimane, R. Poli, and C. Fliedel, "Cobalt (II) and cobalt (III) complexes of tripodal tetradentate diamino-bis (phenolate) ligands: Synthesis, characterization, crystal structures and evaluation in radical polymerization processes," Inorganica Chimica Acta, vol. 549, p. 121408, 2023.
19. M. Li, T. Zhe, F. Li, R. Li, F. Bai, P. Jia, et al., "Hybrid structures of cobalt-molybdenum bimetallic oxide embedded in flower-like molybdenum disulfide for sensitive detection of the antibiotic drug nitrofurantoin," Journal of Hazardous Materials, vol. 435, p. 129059, 2022.
20. E. A. Khalil and G. G. Mohamed, "Preparation, spectroscopic characterization and antitumor-antimicrobial studies of some Schiff base transition and inner transition mixed ligand complexes," Journal of Molecular Structure, vol. 1249, p. 131612, 2022.
21. C. Huang, H. Liao, X. Liu, M. Xiao, S. Liao, S. Gong, et al., "Preparation and characterization of vanillin-chitosan Schiff base zinc complex for a novel Zn2+ sustained released system," International Journal of Biological Macromolecules, vol. 194, pp. 611-618, 2022.
22. D. Huang, Q. Xin, Y. Ni, Y. Shuai, S. Wang, Y. Li, et al., "Synergistic effects of zeolite imidazole framework@graphene oxide composites in humidified mixed matrix membranes on CO2 separation," RSC Advances, vol. 8, pp. 6099-6109, 2018.
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Published
Jun 20, 2023
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Muthana Jasim Jebur, & Yahya F. Al-Khafaji. (2023). Synthesis, Characterization And Finger Print Application Of Zn(II) And Cobalt(II) Complexes With Schiff Base Ligands Derived From benzene-1,2-diamine. Journal of Population Therapeutics and Clinical Pharmacology, 30(15), 295–303. https://doi.org/10.47750/jptcp.2023.30.15.033
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