NiFe2O4@SiO2/SO3H AS A NOVEL AND ENVIRONMENTALLY BENIGN CATALYST FOR THE SYNTHESIS OF SUBSTITUTED IMIDAZOLE SCAFFOLDS.
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Keywords
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Abstract
The development of efficient, sustainable, and environmentally benign catalytic systems remains a central objective in modern synthetic organic chemistry [1,2].
References
1. Anastas, P. T., and Warner, J. C. (1998). Green chemistry: Theory and practice. Oxford University Press.
2. Sheldon, R. A. (2010). Green and sustainable manufacture of chemicals from biomass: State of the art. Green Chemistry, 12(2), 210–219. https://doi.org/10.1039/B921320F
3. Astruc, D., Lu, F., and Aranzaes, J. R. (2005). Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis. Angewandte Chemie International Edition, 44(48), 7852–7872. https://doi.org/10.1002/anie.200500766
4. Bell, A. T. (2003). The impact of nanoscience on heterogeneous catalysis. Science, 299(5613), 1688–1691. https://doi.org/10.1126/science.1083671
5. Schüth, F., Sing, K. S. W., and Weitkamp, J. (2002). Handbook of porous solids. Wiley-VCH.
6. Polshettiwar, V., and Varma, R. S. (2010). Green chemistry by nano-catalysis. Green Chemistry, 12(5), 743–754. https://doi.org/10.1039/B921171C
7. Shylesh, S., Schünemann, V., and Thiel, W. R. (2010). Magnetically separable nanocatalysts: Bridges between homogeneous and heterogeneous catalysis. Angewandte Chemie International Edition, 49(20), 3428–3459. https://doi.org/10.1002/anie.200905684
8. Corma, A. (1997). From microporous to mesoporous molecular sieve materials and their use in catalysis. Chemical Reviews, 97(6), 2373–2419. https://doi.org/10.1021/cr960406n
9. Stein, A., Melde, B. J., and Schroden, R. C. (2000). Hybrid inorganic–organic mesoporous silicates. Advanced Materials, 12(19), 1403–1419. https://doi.org/10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO;2-0
10. Hara, M. (2002). Environmentally benign solid acid catalysts. Chemical Reviews, 102(10), 3791–3810. https://doi.org/10.1021/cr0103566
11. Melero, J. A., van Grieken, R., and Morales, G. (2006). Advances in the synthesis and catalytic applications of organosulfonic-functionalized mesostructured materials. Chemical Reviews, 106(9), 3790–3812. https://doi.org/10.1021/cr050994m
12. Zolfigol, M. A. (2001). Silica sulfuric acid as an efficient and reusable catalyst in organic synthesis. Tetrahedron, 57(46), 9509–9511. https://doi.org/10.1016/S0040-4020(01)00979-0
13. Karimi, B., Abedi, S., Clark, J. H., and Budarin, V. (2006). Sulfonic acid functionalized silica as a recyclable solid acid catalyst. Angewandte Chemie International Edition, 45(29), 4776–4779.
https://doi.org/10.1002/anie.200601199
14. Lu, A.-H., Salabas, E. L., and Schüth, F. (2007). Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angewandte Chemie International Edition, 46(8), 1222–1244.
https://doi.org/10.1002/anie.200602866
15. Polshettiwar, V., Luque, R., Fihri, A., Zhu, H., Bouhrara, M., and Basset, J.-M. (2011). Magnetically recoverable nanocatalysts. Chemical Reviews, 111(5), 3036–3075. https://doi.org/10.1021/cr100230z
16. Goldman, A. (2006). Modern ferrite technology (2nd ed.). Springer.
17. Goya, G. F., Berquó, T. S., Fonseca, F. C., and Morales, M. P. (2003). Static and dynamic magnetic properties of spherical magnetite nanoparticles. Journal of Applied Physics, 94(5), 3520–3528. https://doi.org/10.1063/1.1599959
18. Hu, A., Yee, G. T., and Lin, W. (2005). Magnetically recoverable chiral catalysts immobilized on magnetite nanoparticles. Journal of the American Chemical Society, 127(36), 12486–12487. https://doi.org/10.1021/ja053103s
19. Vestal, C. R., and Zhang, Z. J. (2002). Effects of surface coordination chemistry on magnetic properties of MnFe₂O₄ nanoparticles. Journal of the American Chemical Society, 124(48), 14312–14313. https://doi.org/10.1021/ja027875u
20. Shylesh, S., and Thiel, W. R. (2011). Magnetic nanocatalysts. ChemCatChem, 3(2), 278–287. https://doi.org/10.1002/cctc.201000361
21. Grimmett, M. R. (1997). Imidazole and benzimidazole synthesis. Academic Press.
22. Joule, J. A., and Mills, K. (2000). Heterocyclic chemistry (4th ed.). Blackwell Science.
23. Verma, A., Joshi, S., and Singh, D. (2013). Imidazole: Having versatile biological activities. Journal of Chemistry, 2013(1), 329412. https://doi.org/10.1155/2013/329412
24. Dupont, J., de Souza, R. F., and Suarez, P. A. Z. (2002). Ionic liquid (molten salt) phase organometallic catalysis. Chemical Reviews, 102(10), 3667–3692. https://doi.org/10.1021/cr010338r
25. Sheldon, R. A. (2008). Catalysis: The cornerstone of green chemistry. Chemical Communications, (29), 3352–3365. https://doi.org/10.1039/B803584A
26. Kidwai, M., Saxena, S., Khan, M. K. R., and Thukral, S. S. (2005). Microwave-assisted synthesis of substituted imidazoles. Bioorganic and Medicinal Chemistry Letters, 15(19), 4295–4298. https://doi.org/10.1016/j.bmcl.2005.07.031
27. Heravi, M. M., Derikvand, F., and Bamoharram, F. F. (2006). Heteropolyacid-catalyzed synthesis of substituted imidazoles. Journal of Molecular Catalysis A: Chemical, 242(1–2), 173–175. https://doi.org/10.1016/j.molcata.2005.08.019
28. Varma, R. S. (1999). Solvent-free organic syntheses. Green Chemistry, 1(1), 43–55. https://doi.org/10.1039/A808223E
29. Koukabi, N., Kolvari, E., and Zolfigol, M. A. (2011). Magnetic sulfonic acid catalysts: Efficient and reusable solid acids. Chemical Communications, 47(33), 9230–9232. https://doi.org/10.1039/C1CC12831H
30. Zolfigol, M. A., Khazaei, A., and Mokhlesi, M. (2012). Magnetic solid acid catalysts in organic synthesis. Journal of Organic Chemistry, 77(8), 3640–3645. https://doi.org/10.1021/jo3001386
31. Sagadevan, S., Chowdhury, Z. Z., and Rafique, R. F. (2018). Preparation and characterization of nickel ferrite nanoparticles via co-precipitation method. Materials Research, 21(2), e20160533. https://doi.org/10.1590/1980-5373-MR-2016-0533
32. Stöber, W., Fink, A., & Bohn, E. (1968). Controlled growth of monodisperse silica spheres in the micron size range. Journal of Colloid and Interface Science, 26(1), 62–69. https://doi.org/10.1016/0021-9797(68)90272-5
33. Zolfigol, M. A. (2001). Silica sulfuric acid (SSA) as an efficient and reusable catalyst for organic reactions. Applied Catalysis A: General, 215(1–2), 155–161. https://doi.org/10.1016/S0926-860X(01)00510-7
34. Zolfigol, M. A., Chehardoli, G., Mallakpour, S. E., and Safaiee, M. (2007).
Silica sulfuric acid as an efficient catalyst for the one-pot synthesis of 2,4,5-trisubstituted imidazoles. Journal of Molecular Catalysis A: Chemical, 270(1–2), 219–224.
https://doi.org/10.1016/j.molcata.2007.01.012
2. Sheldon, R. A. (2010). Green and sustainable manufacture of chemicals from biomass: State of the art. Green Chemistry, 12(2), 210–219. https://doi.org/10.1039/B921320F
3. Astruc, D., Lu, F., and Aranzaes, J. R. (2005). Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis. Angewandte Chemie International Edition, 44(48), 7852–7872. https://doi.org/10.1002/anie.200500766
4. Bell, A. T. (2003). The impact of nanoscience on heterogeneous catalysis. Science, 299(5613), 1688–1691. https://doi.org/10.1126/science.1083671
5. Schüth, F., Sing, K. S. W., and Weitkamp, J. (2002). Handbook of porous solids. Wiley-VCH.
6. Polshettiwar, V., and Varma, R. S. (2010). Green chemistry by nano-catalysis. Green Chemistry, 12(5), 743–754. https://doi.org/10.1039/B921171C
7. Shylesh, S., Schünemann, V., and Thiel, W. R. (2010). Magnetically separable nanocatalysts: Bridges between homogeneous and heterogeneous catalysis. Angewandte Chemie International Edition, 49(20), 3428–3459. https://doi.org/10.1002/anie.200905684
8. Corma, A. (1997). From microporous to mesoporous molecular sieve materials and their use in catalysis. Chemical Reviews, 97(6), 2373–2419. https://doi.org/10.1021/cr960406n
9. Stein, A., Melde, B. J., and Schroden, R. C. (2000). Hybrid inorganic–organic mesoporous silicates. Advanced Materials, 12(19), 1403–1419. https://doi.org/10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO;2-0
10. Hara, M. (2002). Environmentally benign solid acid catalysts. Chemical Reviews, 102(10), 3791–3810. https://doi.org/10.1021/cr0103566
11. Melero, J. A., van Grieken, R., and Morales, G. (2006). Advances in the synthesis and catalytic applications of organosulfonic-functionalized mesostructured materials. Chemical Reviews, 106(9), 3790–3812. https://doi.org/10.1021/cr050994m
12. Zolfigol, M. A. (2001). Silica sulfuric acid as an efficient and reusable catalyst in organic synthesis. Tetrahedron, 57(46), 9509–9511. https://doi.org/10.1016/S0040-4020(01)00979-0
13. Karimi, B., Abedi, S., Clark, J. H., and Budarin, V. (2006). Sulfonic acid functionalized silica as a recyclable solid acid catalyst. Angewandte Chemie International Edition, 45(29), 4776–4779.
https://doi.org/10.1002/anie.200601199
14. Lu, A.-H., Salabas, E. L., and Schüth, F. (2007). Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angewandte Chemie International Edition, 46(8), 1222–1244.
https://doi.org/10.1002/anie.200602866
15. Polshettiwar, V., Luque, R., Fihri, A., Zhu, H., Bouhrara, M., and Basset, J.-M. (2011). Magnetically recoverable nanocatalysts. Chemical Reviews, 111(5), 3036–3075. https://doi.org/10.1021/cr100230z
16. Goldman, A. (2006). Modern ferrite technology (2nd ed.). Springer.
17. Goya, G. F., Berquó, T. S., Fonseca, F. C., and Morales, M. P. (2003). Static and dynamic magnetic properties of spherical magnetite nanoparticles. Journal of Applied Physics, 94(5), 3520–3528. https://doi.org/10.1063/1.1599959
18. Hu, A., Yee, G. T., and Lin, W. (2005). Magnetically recoverable chiral catalysts immobilized on magnetite nanoparticles. Journal of the American Chemical Society, 127(36), 12486–12487. https://doi.org/10.1021/ja053103s
19. Vestal, C. R., and Zhang, Z. J. (2002). Effects of surface coordination chemistry on magnetic properties of MnFe₂O₄ nanoparticles. Journal of the American Chemical Society, 124(48), 14312–14313. https://doi.org/10.1021/ja027875u
20. Shylesh, S., and Thiel, W. R. (2011). Magnetic nanocatalysts. ChemCatChem, 3(2), 278–287. https://doi.org/10.1002/cctc.201000361
21. Grimmett, M. R. (1997). Imidazole and benzimidazole synthesis. Academic Press.
22. Joule, J. A., and Mills, K. (2000). Heterocyclic chemistry (4th ed.). Blackwell Science.
23. Verma, A., Joshi, S., and Singh, D. (2013). Imidazole: Having versatile biological activities. Journal of Chemistry, 2013(1), 329412. https://doi.org/10.1155/2013/329412
24. Dupont, J., de Souza, R. F., and Suarez, P. A. Z. (2002). Ionic liquid (molten salt) phase organometallic catalysis. Chemical Reviews, 102(10), 3667–3692. https://doi.org/10.1021/cr010338r
25. Sheldon, R. A. (2008). Catalysis: The cornerstone of green chemistry. Chemical Communications, (29), 3352–3365. https://doi.org/10.1039/B803584A
26. Kidwai, M., Saxena, S., Khan, M. K. R., and Thukral, S. S. (2005). Microwave-assisted synthesis of substituted imidazoles. Bioorganic and Medicinal Chemistry Letters, 15(19), 4295–4298. https://doi.org/10.1016/j.bmcl.2005.07.031
27. Heravi, M. M., Derikvand, F., and Bamoharram, F. F. (2006). Heteropolyacid-catalyzed synthesis of substituted imidazoles. Journal of Molecular Catalysis A: Chemical, 242(1–2), 173–175. https://doi.org/10.1016/j.molcata.2005.08.019
28. Varma, R. S. (1999). Solvent-free organic syntheses. Green Chemistry, 1(1), 43–55. https://doi.org/10.1039/A808223E
29. Koukabi, N., Kolvari, E., and Zolfigol, M. A. (2011). Magnetic sulfonic acid catalysts: Efficient and reusable solid acids. Chemical Communications, 47(33), 9230–9232. https://doi.org/10.1039/C1CC12831H
30. Zolfigol, M. A., Khazaei, A., and Mokhlesi, M. (2012). Magnetic solid acid catalysts in organic synthesis. Journal of Organic Chemistry, 77(8), 3640–3645. https://doi.org/10.1021/jo3001386
31. Sagadevan, S., Chowdhury, Z. Z., and Rafique, R. F. (2018). Preparation and characterization of nickel ferrite nanoparticles via co-precipitation method. Materials Research, 21(2), e20160533. https://doi.org/10.1590/1980-5373-MR-2016-0533
32. Stöber, W., Fink, A., & Bohn, E. (1968). Controlled growth of monodisperse silica spheres in the micron size range. Journal of Colloid and Interface Science, 26(1), 62–69. https://doi.org/10.1016/0021-9797(68)90272-5
33. Zolfigol, M. A. (2001). Silica sulfuric acid (SSA) as an efficient and reusable catalyst for organic reactions. Applied Catalysis A: General, 215(1–2), 155–161. https://doi.org/10.1016/S0926-860X(01)00510-7
34. Zolfigol, M. A., Chehardoli, G., Mallakpour, S. E., and Safaiee, M. (2007).
Silica sulfuric acid as an efficient catalyst for the one-pot synthesis of 2,4,5-trisubstituted imidazoles. Journal of Molecular Catalysis A: Chemical, 270(1–2), 219–224.
https://doi.org/10.1016/j.molcata.2007.01.012
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Sep 26, 2014
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How to Cite
K. R. Kadam, A. S. Waghmare, S. N. Shringare, & D. S. Wankhede. (2014). NiFe2O4@SiO2/SO3H AS A NOVEL AND ENVIRONMENTALLY BENIGN CATALYST FOR THE SYNTHESIS OF SUBSTITUTED IMIDAZOLE SCAFFOLDS. Journal of Population Therapeutics and Clinical Pharmacology, 21(3), 534-544. https://doi.org/10.53555/5gn6vj72
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Author Biographies
K. R. Kadam
Department of Chemistry and Research Laboratory, Padmashri Vikhe Patil College, Pravaranagar, Ahilyanagar-413713, (Maharashtra) India.
A. S. Waghmare
School of Chemical Sciences, Punyashlok Ahilydevi Holkar Solapur University, Solapur-413255, (Maharashtra) India.
S. N. Shringare
School of Chemical Sciences, Punyashlok Ahilydevi Holkar Solapur University, Solapur-413255, (Maharashtra) India.
D. S. Wankhede
School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, nanded-431605, (Maharashtra), India
How to Cite
K. R. Kadam, A. S. Waghmare, S. N. Shringare, & D. S. Wankhede. (2014). NiFe2O4@SiO2/SO3H AS A NOVEL AND ENVIRONMENTALLY BENIGN CATALYST FOR THE SYNTHESIS OF SUBSTITUTED IMIDAZOLE SCAFFOLDS. Journal of Population Therapeutics and Clinical Pharmacology, 21(3), 534-544. https://doi.org/10.53555/5gn6vj72
